NFPA Hazard Ratings:

Ingredients not precisely identified are proprietary and/or non-hazardous. All chemical ingredients appear on the EPA TSCA inventory.

• Signs and Symptoms of Acute Overexposure: Eye, skin irritation
• Signs and Symptoms of Chronic overexposure: Dermatitis and skin sensitization
• Medical Conditions Generally Aggravated by Exposure: Allergies, dermatitis.
• Ingestion: No effect if ingested in small amounts. Relative to other materials, a single dose of this product is rarely toxic by ingestion. Irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion.

• Inhalation: Remove victim to fresh air
• Ingestion: Give victim water or milk to drink to dilute the product. Get medical advice..
• Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
• Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
• Note to Physician: If patient's immune system is compromised, request antibiotic sensitivity chart from Alken-Murray Corporation by e-mail: msds@alken-murray.com. Nitrates in large doses may cause significant vasodilation and hypotension. Pre-existing ischemic heart disease may be aggravated by these effects. In large ingestions, nitrates may cause methemoglobinemia. Methemoglobinemia should be suspected if cyanosis occurs. Methyl blue (1-2 mg/kg I.V.over several minutes) is an effective antidote for symptomatic methemoglobinemia.

 Flash Point: NA

Flammability Limits: NA

Autoignition temp: NA

Fire Extinguishing Media: Water spray, carbon dioxide, dry chemical

Special Fire-Fighting Information: None

Unusual Fire and Explosion Hazards: Nitrate salts can support combustion under certain conditions. Do not allow product to evaporate to drynes. For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear.

• Ventilation System: Good general ventilation is advisable
• Personal Respirators (NIOSH Approved): if needed, use respirator to screen out nuisance dust
• Skin Protection: Long sleeved clothing
• Eye Protection: Safety glasses if mist is formed indoors.
• Other Control Measures: Minimize exposure in accordance with good hygiene practice. Avoid handling which would create large amounts of dust.

  OSHA: CAS 7664-41-7: TWA: 35 mg//M3, STEL: 25 mg//M3/ 67-63-0: 400 ppm, / 1310-73-2: 2 mg/M3

  ACGIH: CAS 7664-41-7TWA: 25 ppm, STEL: 35 ppm/ 67-63-0: 400 ppm/ 1310-73-2: 2 mg/M3

• Appearance and Color: Opaque forest green liquid.
• Odor: Wild hyacinth fragrance added
• Solubility in Water: 99%
• Specific Gravity: 1.043 @ 15 deg. C
• Bulk density: NDA
• pH: 6.5-7.5
• % volatile by volume @ 21C (70F): Nil
• Boiling Point: 212 degrees F, 100 degrees C
• Melting Point: 32 degrees F
• Vapor Density (Air=1): =water
• Vapor Pressure (mm Hg): =water
• Evaporation Rate (Bu. Acetate=1): =water

• Stability: Product is stable.
• Hazardous Decomposition Products: None
• Hazardous Polymerization: will not occur.
• Incompatibility: Acids, alkalies, other toxic materials may inactivate biological cultures.
• Conditions to Avoid: Incompatible substances

• Toxicological Data:

RTECS: CAS# 7664-41-7: BO0875000/Bacterial cultures: 1003657BA/ CAS 7732-18-5: ZC0110000/ CAS 2634-33-5: 1004600BE/ CAS 1310-73-2: WB4900000/ CAS 25265-71-8: UB8765000/ CAS 64-02-8: AH5075000/CAS# 134-20-3: CB3325000 AH5075000/CAS# 9004-82-4: WB7499000/ CAS# 61789-40-0: 1007217CB/ Fragrance: 1002064FR/ CAS# 67-63-0: NT8050000

LD50/LC50 for Individual Ingredients - CAS# 7732-18-5: LD50= >90 mL/Kg / CAS# 61789-40-0: Oral, mouse LD50 = 4900 mg/Kg; Dermal,albino rabbif LD50 = > 2000 mg/Kg / CAS# 9004-82-4: Oral, rat LD50 = 1620 mg/Kg / CAS# 223749-05-1 (Yucca schidigera) - Oral, mouse, LC50 of a 70% solution = > 5000 mg/kg ./ CAS# 7664-41-7: inhalation, mouse LC50 = 4230 ppm/1H, inhalation, mouse LC50 = 4600 mg/M3/2H, inhalation, rabbit LC50 = 7g/M3/1H, inhalation, rat LC50 = 2,000 ppm/4H, inhalation, rat LC50 = 18600 mg/M3/5H, skin, rat LC50 = 112, 000 mg/M3/15H / CAS# 68140-00-1:Oral, rat LD50 = 1200 mg/Kg / Blue polymer dye: Oral, rat LD50 = >5,000 mg/Kg, Comment: Extremely low toxicity to rats/ CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit = 12800 mg/Kg / CAS# 2634-33-5, oral, rat LD50 = 20 g/Kg / CAS# 1310-73-2: skin, rabbit: 500 mg/24H severe; eye rabbit: 50 ug/24H severe / CAS 25265-71-8 eye-rabbit 510 mg skin-rabbit 500 mg/24H MLD; LD50 oral rat 14850 mg/kg; LD50 oral guinea pig 17600 mg/kg / CAS# 64-02-8: Oral, rat LD50 = > 1,000 mg/Kg; Oral, rabbit, LD50 = > 2,000 mg/Kg / CAS# 134-20-3: Oral, rat LD50 =:3000 mg/kg, Oral, mouse LD50 = 3900 mg/kg, Oral LD50 Guinea pig:

Dermal & Eye Irritation Tests for Proprietary "Oxygenated organic/inorganic salts Solution" - sold as ALKEN® 896 BIOSTIMULANT
Acute dermal irritation study New Zealand white rabbits: A 20% solutionm (5 ml "Oxygenated organic/inorganic salts Solution" + 20 mL sterile, distilled water) was applied to intact & abraded skin one one side, with sterile water applied to intact & abraded skin on other side of same animals to serve as controls.
Acute dermal irritation New Zealand white rabbits: PI = 0.0, Toxicity level IV
Acute eye irritation: A 20% solution (5 ml "Oxygenated organic/inorganic salts Solution" + 20 mL sterile, water) was introduced to one eye, while untreated eye was observed as a "control". Eyes were examined and graded at 24, 48 and 72 hours post treatment..
Acute eye irritation, :New Zealand white rabbits: PI=0.0, Toxicity IV

Bacteria in this product: Acute oral toxicity: Rats LD50 = > 5 grams/kg, no toxicity symptoms, no weight loss

Acute dermal toxicity: LD50 = > 5050 mg/Kg

Acute dermal irritation albino rabbits: PI = 0.0, Toxicity level IV

Acute eye irritation: PI = 0.0, Toxicity IV
Acute Inhalation, Rats LC50 = >2.43 mg/L.

• Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

• Environmental Fate: This product is not likely to bio-concentrate, if mixed with water. This product released directly or indirectly into the environment is not expected to have a significant impact.
• Environmental Toxicity: This material has a low potential to affect aquatic organisms, secondary waste treatment microorganisms, and the growth of some plants. Coconut amine surfactants including CAS 6178-40-0, CAS 68140-00-1 and CAS 9004-80-4 present low volatility and an aquatic LC50 of 0.2 to 59 mg/L and since the included bacteria use them as a food source, minimal environmental impact is expected. Low volatility, water soluble formula.
  
• Aquatic Ecotoxicity of Individual Ingredients: CAS# 2634-33-1, 1,2 benzisothiazolin-3-one (<1%) is VERY toxic to aquatic organisms (Fish, LC50, 4 days exposure = 1.0 - 3.3 ppm. Crustaceans
  
• Biodegradability: CAS# 2634-33-1 will biodegrade by 81.9% within 20 days.
  

• DOT Proper Shipping Name: Not regulated as hazardous by DOT
• DOT Hazard Class: None
• DOT Label: The proper shipping name for UNREGULATED SHIPMENT via DOT and TDG is as follows: "Class 55 (Item 048580, sub 3): "Cleaning or washing compound NOI, liquid, in drums or pails".

• TSCA: (40CFR 710) All chemical ingredients are listed on the TSCA 8(b) inventory. None of the ingredients are on the Health and Safety Reporting List, are under Chemical Test rule, are listed under TSCA Section 12B, or have a SNUR under TSCA
• CERCLA Reportable Quantity: This product does NOT contain ingredients that have Reportable Quantity (RQ) requirements under US 40 CFR 117.302
• SARA TITLE III:

  Section 302/304 Extremely Hazardous Substances: None Section 311 Hazard Categorization: Acute, chronic Section 313 Toxic Chemicals: This material contains sodium hydroxide (CAS 1310-73-2) which is subject to reporting requirements of Section 313 or Sara Title III and 40 CFR Part 373. 1,000 lb Final RQ (454 Kg). This ingredient represents less than 1% of final product formula, which has a neutral pH, thereby avoiding ALL issues that could lead to the need for a reporting incident. At less than 1% of finished formula, a total weight of 1,000 lbs sodium hydroxide would be included in 100,000 lbs of liquid product with NEUTRAL pH.

• Clean WaterAct: This product contains CAS # 1310-73-2, sodium hydroxide, a chemical that CWA lists as a "hazardous substance", but CWA does NOT list ANY product ingredient on their "Priority Pollutant" or "Toxic Pollutant" lists..
• Clean AirAct : This product does not contain any Class 1 or Class 2 ozone depletors, nor was it made with such chemicals.
• OSHA: Sodium hydroxide IS considered "Extremely Hazardous" by OSHA.
• STATE RIGHT-TO-KNOW LAWS: Dipropylene glycol (< 1%), CAS# 25265-71-8 IS found on the Pennsylvania RTK list. Glycerine (2.5%), CAS# 56-81-5 IS found on the following RTK lists: Pennsylvania, Minnesota & Massachussetts.. Sodium hydroxide, CAS 1310-73-2, comprising < 1% of this product can be found on the following RTK lists: California, New Jersey, Florida, Pennsylvania, Minnesota & Massachusetts. Other ingredients ARE NOT listed on the following RTK lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, or Rhode Island.
• Not subject to California Proposition 65 labeling requirements
• Canadian WHMIS Class D2B. (Other toxic effects - for surfactants & imported LIVE microbial cultures). CAS# 27176-87-0, 1310-73-2 & 64-02-8 (combined at < 1%) normally add a "Class E" to products containing them, but the neutral pH of THIS product exempts it from this addition.
• Canadian DSL: All ingredients listed. Approved for sale in Canada
• Canada's Ingredient Disclosure List: Sodium hydroxide, CAS 1310-73-2, comprising <1% of this product IS listed on the CIDL, but other ingredients are "NOT CONTROLLED". . This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
• TDG Classification: This product is not subject to "hazardous goods" descriptions and transport surcharges.
  
  

Reason for Revision: Routine review & revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.